1-[3-({[Bis(2-methylpropyl)carbamothioyl]amino}carbonyl)benzoyl]-3,3-bis(2-methylpropyl)thiourea
نویسندگان
چکیده
The title compound, C26H42N4O2S2, adopts a shallow U-shape as both pendant arms of the 1,3-substituted benzene ring are orientated in the same direction. The thione S atoms lie to the same side of the benzene ring and the carbonyl O atoms to the other. The most prominent feature of the crystal packing is the formation of inversion dimers mediated by N-H⋯S hydrogen bonds. One of the 2-methyl-propyl groups is statistically disordered over two positions.
منابع مشابه
1-Benzoyl-3,3-bis(2-methylpropyl)thiourea
The title compound, C(16)H(24)N(2)OS, is twisted about the central N(H)-C bond with the C-N-C-S torsion angle being 119.6 (3)°. The carbonyl O and thione S atoms are directed to opposite sides of the mol-ecule, a conformation that allows for the formation of a linear supra-molecular chain comprising alternating eight-membered {⋯HNCS}(2) and 14-membered {⋯HCNCNCO}(2) synthons.
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In the mol-ecule of the title compound, C34H36O4, the two 4-isobutyl-benzoyl groups at the 1- and 8-positions of the naphthalene ring system are aligned almost anti-parallel, and the benzene rings make a dihedral angle of 21.59 (7)°. The dihedral angles between the benzene rings and the naphthalene ring system are 69.26 (6) and 64.29 (5)°. There are no classical hydrogen bonds in the structure,...
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